This protocol outlines the methodology for conducting Scanning Electron Microscopy (SEM) and Energy-Dispersive X-ray Spectroscopy (EDS) analysis of laser-inscribed graphene (LIG) electrodes using a SU5000 microscope. The procedure details the preparation of LIG electrodes, their imaging under SEM, and subsequent elemental analysis via EDS. By combining SEM imaging for morphology assessment with EDS for elemental composition identification, this protocol facilitates a comprehensive characterization of LIG electrodes, crucial for understanding their structural features and properties in various applications. The fusion of SEM and EDS techniques offers insights into the intricate structure-property relationships of LIG electrodes, advancing their potential in diverse fields such as energy storage, sensing, and electronics.